COMBUSTION SYNTHESIS AND CHARACTERIZATION OF DYSPROSIUM NANO-COMPOSITE MELILITE FOR DIODE APPLICATIONS

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Published: 2022-12-31

DOI: 10.56557/japsi/2022/v14i28046

Page: 53-66


MOSIORI, CLIFF ORORI *

Department of Mathematics and Physics, School of Applied and Healthy Sciences, Technical University of Mombasa, P. O. Box 92840, Mombasa, Kenya.

*Author to whom correspondence should be addressed.


Abstract

Light emitting nano-scale materials have attracted a great interest in recent days. In view of this, a nanocrystal solid luminescent composite material was prepared using combustion processing technique and its identity was analyzed and further investigated. The precursor reagents were measured using the single pan analytical balance. A sample was synthesized and its functional group was identified using the FTIR spectroscopy and XRD studies as having similar properties to those in Batch No. JCPDS No. 77-1149 and in Base Code AMCSD 0008032. Its photoluminescence spectrum identified peaks located at 476 nm, 578 nm and 615 nm that were attributed to electronic transition from 4F9/2 to 6H15/2, from 4F9/2 to 6H13/2 and from 4F9/2 to 6H11/2 respectively as the finger blue-prints of dysprosium [Dy3+] ion. Its crystalline sizes and strains were calculated using the Debay Scherrer’s equation and analyzed using the UDM model. The findings showed that the prepared sample had a superior homogeneity and further that the Dy3+ influenced its formation. The melllite sample was identified to be Ca2MgSi2O7:Dy3+. Further analysis on the sample suggested that was a potential white light emitting luminescent material just like Ca2MgSi2O7:Tb3+ phosphor and Sr2MgSi2O7:Dy3+ phosphor.

Keywords: Debay Scherrer’s, XRD, UDM model, strain, photoluminescence, Ca2MgSi2O7:Dy3


How to Cite

ORORI, MOSIORI, CLIFF. 2022. “COMBUSTION SYNTHESIS AND CHARACTERIZATION OF DYSPROSIUM NANO-COMPOSITE MELILITE FOR DIODE APPLICATIONS”. Journal of Applied Physical Science International 14 (2):53-66. https://doi.org/10.56557/japsi/2022/v14i28046.

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