INVESTIGATION OF CORROSION INHIBITOR ADSORPTION ON STAINLESS STEEL USING BENZALDEHYDE SEMICARBAZONE

Main Article Content

IMPERIYKA, M. HAMMAD
RAHUMA, N. MOHAMED
JAZEA B. RAMADAN

Abstract

The influence of benzaldehyde semicarbazone on corrosion through stainless steel in 11% HCl has been studied using weight loss measurements and scanning electron spectroscopy. The inhibition efficiency of benzaldehyde semicarbazone was found to vary with concentration, temperature and immersion time. The inhibition efficiency increases with increasing of inhibitor concentration. Good inhibition efficiency (IE) was evidenced in acid solutions, the inhibition efficiency was found to be 81.56% in 11% HCl of the 0.04 inhibitor concentration at 45°C for 5 days. Adsorption of inhibitor on the steel surface follows Langmuir adsorption isotherm. The mechanism of physical adsorption is proposed from the inhibitory action of benzaldehyde semicarbazone is satisfactorily explained by thermodynamic and kinetic parameters such as ΔH°, ΔS°, ΔG° and Ea are calculated. All the experiments show good agreements. Scanning electron spectroscopy technique is used to observe the surface morphology of mild steel samples in the presence and absence of benzaldehyde semicarbazone at optimum conditions. In the presence of benzaldehyde semicarbazone, scanning electron microscope exposes the formation of a smooth and dense protective layer on surface of mild steel. The values of activation energy and free energy of adsorption indicated chemisorption adsorption on 304 stainless steel surface.

Keywords:
Benzaldehyde semicarbazone, corrosion inhibition, Langmuir adsorption, stainless steel

Article Details

How to Cite
HAMMAD, I. M., MOHAMED, R. N., & RAMADAN, J. B. (2021). INVESTIGATION OF CORROSION INHIBITOR ADSORPTION ON STAINLESS STEEL USING BENZALDEHYDE SEMICARBAZONE. Journal of Applied Chemical Science International, 12(1), 6-16. Retrieved from https://www.ikprress.org/index.php/JACSI/article/view/6354
Section
Original Research Article

References

Dahiya SS, Kumar S, Mehta SC, Singh R, Nath K, Narnaware SD, Tuteja FC. Molecular characterization of camelpox virus isolates from Bikaner, India: Evidence of its endemicity. Acta Tropica. 2017;171:1-5.

Kumari WGP, Ranjith PG, Perera MSA, Chen BK, Abdulagatov IM. Temperature-dependent mechanical behaviour of Australian Strathbogie granite with different cooling treatments. Engineering Geology. 2017;229: 31-44.

Bui BV, Downie LE, Lindsay RG. Optical coherence tomography: seeing the unseen. Clinical and Experimental Optometry. 2019; 102(3):193-194.

Khaled KF. Electrochemical investigation and modeling of corrosion inhibition of aluminum in molar nitric acid using some sulphur-containing amines, Corrosion Science. 2010; 52:2905–2916.

Palayoor V, Kakkassery T, Kanimangalath S. Varghes S. Int. J. Iind. Chem. 2017;8(1):49–60.

Chaudhari NM, Gupta VK, Dutta C. BPGA-an ultra-fast pan-genome analysis pipeline. Scientific Reports. 2016;6(1):1-10.

Ibrahim MN, AL-Difar HA. Synthesis and antibacterial activity of semicarbazone derivativesof some carbonyl compounds. Der Chemica Sinica. 2011;2.

Singh S. Statistical methods for research workers. Kalyani Pub; 2010.

Rajak H, Deshmukh R, Veerasamy R, Sharma AK, Mishra P, Kharya MD. Novel semicarbazones based 2, 5-disubstituted-1, 3, 4-oxadiazoles: One more step towards establishing four binding site pharmacophoric model hypothesis for anticonvulsant activity. Bioorganic & Medicinal Chemistry Letters. 2010;20(14):4168-4172.

Padhye J, Agarwal S, Padmanabhan VN, Qiu L, Rao A, Zill B. Estimation of link interference in static multi-hop wireless networks. In Proceedings of the 5th ACM SIGCOMM conference on Internet Measurement. USENIX Association. 2005;28-28.

Amir M, Ahsan MJ, Ali I. Synthesis of N 1 -(3- chloro-4-flurophenyl)-N 4 -semicarbazones as novel anticonvulsant agents. Indian J Chem. 2010;49B:1509-1514.

Rajak SN, Collin JRO, Burton MJ. Trachomatous trichiasis and its management in endemic countries. Survey of Ophthalmology. 2012;57(2):105-135.

Dimmock JR, Kandepu NM, Nazarali AJ, Kowalchuk TP, Motaganahalli N, Quail JW, Allen TM. Conformational and quantitative structure− activity relationship study of cytotoxic 2-arylidenebenzocycloalkanones. Journal of Medicinal Chemistry. 1999;42(8): 1358-1366.

Dutta, Achyut. High speed electrical on-chip interconnects and method of manufacturing. U.S. Patent Application 10/904,723, Filed; 2005.

Govindasamy R, Ayappan S. Study of corrosion inhibition properties of novel semicarbazones on mild steel in acidic solutions. Journal of the Chilean Chemical Society. 2015;60(1):2786-2798.

Okafor-Dike LC. The effect of leadership on economic development: A case study of Nigeria (Doctoral dissertation, University of Phoenix); 2008.

Fouda AE, Teixeira FL, Yavuz ME. Time-reversal techniques for MISO and MIMO wireless communication systems. Radio Science. 2012;47(06):1-15.

Vinod PR, Joby TK, Shaju KS, Aby P. Corrosion inhibition investigations of 3-acetylpyridine semicarbazone on carbon steel in hydrochloric acid medium. Res Chem Intermed. 2014;40(8):2689–2701.

Singh VB, Ray M. Effect of H2SO4 addition on the corrosion behaviour of AISI 304 austenitic stainless steel in methanol-HCl solution. Int. J. Electrochem. Sci. 2007;2:329-340.

Ahsana MJ, Samya JG, Khalilullaha H, Md. S. Nomania. Pelagia Research Library Der Pharmacia Sinica. 2011;2(6):107-113.
ISSN: 0976-8688.

Farooqi IS, Jebb SA, Langmack G, Lawrence E, Cheetham CH, Prentice AM, O'Rahilly S. Effects of recombinant leptin therapy in a child with congenital leptin deficiency. New England Journal of Medicine. 1999;341(12):879-884.

Rahuma KM, Mohamed H, Hissein N, Giuma S. Prediction of reservoir performance applying decline curve analysis. International Journal of Chemical Engineering and Applications. 2013; 4(2):74.

Achary G, Sachin HP, Naik YA, Venkatesha TV. The corrosion inhibition of mild steel by 3-formyl-8-hydroxy quinoline in hydrochloric acid medium. Materials Chemistry and Physics. 2008;107(1):44-50.

Khaled KF, Hackerman N. Investigation of the inhibitive effect of ortho-substituted anilines on corrosion of iron in 1 M HCl solutions. Electrochimica Acta. 2003;48(19):2715- 2723.

El-Maksoud SA. The effect of organic compounds on the electrochemical behaviour of steel in acidic media. A review. International Journal of Electrochemical Science. 2008;3(5): 528-555.

Popova A, Sokolova E, Raicheva S, Christov M. AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives. Corrosion Science. 2003;45(1):33-58.

Gopiraman M, Jatoi AW, Hiromichi S, Yamaguchi K, Jeon HY, Chung IM, Soo KI. Silver coated anionic cellulose nanofiber composites for an efficient antimicrobial activity. Carbohydrate Polymers. 2016;149:51-59.

Sahin M, Bilgic S, Ylmaz H. The inhibition effects of some cyclic nitrogen compounds on the corrosion of the steel in NaCl mediums. Applied Surface Science. 2002;195.

Noor MA, Shah FA, Noor KI, Al-Said E. Variational iteration technique for finding multiple roots of nonlinear equations. Sci. Res. Essays. 2011;6(6):1344-1350.

Atkins P. "Physical chemistry" Oxford University Press, New York; 1999.

Kamis E, Belluci F, Latanision RM, El-Ashry ESH. Acid corrosion inhibition of nickel by 2-(Triphenosphoranylidene) succinic anhydride. Corrosion Science. 1991;47.

El‐Awady AA, Abd‐El‐Nabey BA, Aziz SG. Kinetic‐thermodynamic and adsorption isotherms analyses for the inhibition of the acid corrosion of steel by cyclic and open‐chain amines. Journal of the Electrochemical Society. 1992;139(8):2149-2154.

Li Y, Tang WK, Chen G. Hyperchaos evolved from the generalized Lorenz equation. International Journal of Circuit Theory and Applications. 2005;33(4):235- 251.

Singh AK, Quraishi MA. Effect of 2, 2′ benzothiazolyl disulfide on the corrosion of mild steel in acid media. Corrosion Science. 2009;51(11):2752-2760.

Roberge P. Handbook of corrosion engineering. McGraw-Hill Company, Inc., New York; 2000.

Thomas JM, Thomas WJ. Introduction to the principles of heterogeneous catalysis. 5th Edition, Academic Press, London; 1981.

Allen JB, Faulkner LR. Electrochemical methods: fundamentals and applications. 2nd Edition, Wiley. 2000;18.